Not all silicon wafer suppliers operate the same way, and the difference between a manufacturer and a distributor affects far more than where the invoice comes from. Picking the wrong type for a given project usually shows up later, either in the price paid or in how long an order actually takes to arrive.
Our own silicon wafer products page lists what we produce directly, which is a useful starting point for understanding how a manufacturer-direct model actually works.

Pricing is the most obvious difference between these two types of silicon wafer suppliers. A distributor buys finished wafers from a manufacturer, adds a markup, and resells them, which covers the cost of holding inventory and providing local support.
Going directly to a manufacturer removes that layer, and according to Thomasnet, buying directly generally results in lower costs because no intermediary margin is added to the price. That gap tends to matter most at volume, less so for a single small order.
Lead time works in the opposite direction more often than people expect. Distributors can sometimes ship faster for standard, in-stock configurations because the wafer is already in stock.
Manufacturers need real production time for anything outside their existing inventory. Still, that time buys something a distributor cannot offer: a wafer built to your exact diameter, doping, and thickness rather than the closest available match.
Technical support is where the difference becomes most noticeable during an actual project. A manufacturer's engineers know the process capability firsthand, since they run it. A distributor selling wafers made elsewhere has to relay technical questions back to the source, which adds a step and sometimes a delay to getting a real answer about feasibility or tolerance.
A rough way to sort a given order between the two:

Wafer World fabricates wafers directly, which means custom specifications go straight to the people who actually run the process, not through a reseller relaying your questions.
Request a quote and talk through your specific requirements with our team directly, the same kind of direct access you would expect from any silicon wafer suppliers you consider.